Poly[piperazine-1,4-diium [μ4-chlorido-μ3-chlorido-tri-μ2-chlorido-chloridodicadmate(II)] monohydrate]
نویسندگان
چکیده
منابع مشابه
Poly[piperazine-1,4-diium [μ4-chlorido-μ3-chlorido-tri-μ2-chlorido-chloridodicadmate(II)] monohydrate]
In the title compound, {(C(5)H(14)N(2))[Cd(2)Cl(6)]·H(2)O}(n), the asymmetric unit contains one piperazinediium cation, one [Cd(2)Cl(6)](2-) anion and a water mol-ecule. The coordination geometries of the two Cd(2+) cations are distorted octa-hedral. Adjacent Cd(II) atoms are inter-connected alternately by paired chloride bridges, generating polymeric chains parallel to [010]. Neighbouring chai...
متن کاملPentakis(2-oxo-2,3-dihydropyrimidin-1-ium) di-μ3-chlorido-tri-μ2-chlorido-hexachloridotricadmate(II)
The title compound, (C(4)H(5)N(2)O)(5)[Cd(3)Cl(11)], was obtained from the reaction of 2-hydroxy-pyrimidine hydro-chloride and cadmium(II) chloride in concentrated HCl solution. The crystal structure consists of planar 2-oxo-1,2-dihydro-pyrimidin-3-ium cations with both N atoms protonated and the O atom unprotonated, and a complex trinuclear [Cd(3)Cl(11)](5-) anion of approximately D(3h) symmet...
متن کاملDi-μ3-chlorido-tetra-μ2-chlorido-dichloridobis(dimethylformamide-κO)hexakis(1H-imidazole-κN 3)tetracadmium
The centrosymmetric mol-ecule of the title complex, [Cd(4)Cl(8)(C(3)H(4)N(2))(6)(C(3)H(7)NO)(2)], contains four Cd(II) atoms, six imidazole, two dimethyl-formamide and eight chloride ligands. The structure shows a novel chloride-bridged tetra-nuclear cadmium quasi-cubane cluster. The coordination geometry of all Cd(II) atoms is distorted octa-hedral, with the two metal atoms in the asymmetric u...
متن کاملPoly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]
The title compound, [Pb(4)(C(8)H(4)O(4))(3)Cl(2)](n), consists of a three-dimensional inorganic-organic hybrid framework. The asymmetric unit contains two Pb(2+) cations, one Cl(-) anion and one and a half terephthalate anions, the latter being completed by inversion symmetry. The two Pb(2+) cations are each surrounded by five O atoms and one Cl atom in the form of irregular polyhedra. The cati...
متن کاملDi-μ2-chlorido-bis[chlorido(η6-hexamethylbenzene)ruthenium(II)]
Dimeric mol-ecules of the title compound, [Ru(2)Cl(4)(C(12)H(18))(2)], are located on a crystallographic centre of inversion with one mol-ecule in the asymmetric unit. The hexa-methyl-benzene rings are in an η(6)-coordination to the ruthenium centres, which are bridged by two chloride ligands. In addition, the ruthenium centres are bonded to another chloride ligand. The aromatic rings and the R...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812001626